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万贤楷     特聘研究员,博导

研究方向:物理化学;团簇化学;无机化学

联系方式:          Email:xkwan@scu.edu.cn

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简历:

学习及工作经历

2021.06— 至今 威人斯尼登录网,特聘研究员,博士生导师

2018.10—2021.04 名古屋大学,JSPS特别研究员,合作导师:Mizuki Tada教授

2017.09—2018.09 南洋理工大学,博士后研究员,合作导师:楼雄文 教授

2011.09—2017.07 厦门大学化学化工学院,理学博士,导师:王泉明 教授

2007.09—2011.07 重庆大学化学化工学院,工学学士

主要研究方向

金属团簇化学

金属纳米团簇精准合成

金属纳米团簇发光与催化性质研究及应用

课题组诚招博士后、博士、硕士研究生、研究助理以及联合培养学生,欢迎对物理化学、团簇化学、无机化学、材料学、团簇催化、电化学、晶体学等感兴趣的学生加入本课题组。

主要工作业绩

金属团簇化学、团簇催化应用与光学性质研究

主要从事金属纳米团簇精准合成、表征以及发光、光热、催化应用等性质研究。包括创新性的采用直接还原前驱体法和混合配体保护策略构筑结构与性质新颖的币金属纳米团簇,研究团簇稳定机制、建立明确构-效关系;强近红外发光与光热转化金属团簇材料精准构筑与应用研究;纳米团簇催化应用:热催化转化(催化选择性加氢和偶联反应),电催化转化(电解水制氢、二氧化碳还原和氧还原等)。截至目前已发表学术论文20余篇,以第一作者在Sci. Adv.Nat. Commun.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Adv. Mater.Dalton. Trans.等杂志发表多篇论文,累积引用超过2800次,其中包括ESI高被引、VIPEditor Choicehot paper

主要奖励和荣誉

2023 入选四川大学青年科技学术带头人培育项目

2022 入选四川省天府峨眉计划青年项目

2021 入选四川大学双百B人才项目

2019 入选日本学术振兴会(JSPS)特别研究员项目

2017 厦门大学优秀毕业生

代表性成果 (获奖成果、专著、论文、专利)

1. Xian-Kai Wan, Xu-Shuang Han, Zong-Jie Guan, Wan-Qi Shi, Jiao-Jiao Li, and Quan-Ming Wang*. Interplay of kernel shape and surface structure for NIR luminescence in atomically precise gold nanorods, Nat. Commun. 2024, 15, 7214.

2. Xian-Kai Wan, Jia-Qi Wang, and Quan-Ming Wang*. Ligand-Protected Au55 with a Novel Structure and Remarkable CO2 Electroreduction Performance, Angew. Chem. Int. Ed. 2021, 60, 20748. (hot paper)

3. Xian-Kai Wan, Gabor Samjeské*, Hirosuke Matsui, Chaoqi Chen, Satoshi Muratsugu, Mizuki Tada*. Ultrafine Pt-Ni Nanoparticles in Hollow Porous Carbon Spheres for Remarkable Oxygen Reduction Reaction Catalysis. Dalton. Trans. 2021, 50, 6811-6822. (back cover)

4. Xian-Kai Wan,# Hao Bin Wu,# Bu Yuan Guan, Deyan Luan, and Xiong Wen (David) Lou*. Confining Subnanometer Pt Clusters in Hollow Mesoporous Carbon Spheres for Boosting Hydrogen Evolution Activity, Adv. Mater. 2020, 32, e1901349. (ESI 高被引论文)

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5. Xian-Kai Wan, Jia-Qi Wang, Zi-Ang Nan and Quan-Ming Wang*. Ligand Effects in Catalysis by Atomically Precise Gold Nanoclusters, Sci. Adv. 2017, 3, e1701823. (ESI 高被引论文)

6. Xian-Kai Wan, Zong-Jie Guan, and Quan-Ming Wang*. Homoleptic Alkynyl-Protected Gold Nanoclusters: Au44(PhCC)28 and Au36(PhCC)24, Angew. Chem. Int. Ed. 2017, 56, 11494. (VIP文章)

7. Xian-Kai Wan, Xiao-Ling Cheng, Qing Tang, Ying-Zi Han, Guoxiang Hu,, De-En Jiang*, and Quan-Ming Wang*. Atomically Precise Bimetallic Au19Cu30 Nanocluster with an Icosidodecahedral Cu30 Shell and an Alkynyl–Cu Interface, J. Am. Chem. Soc. 2017, 139, 9451-9454.

8. Xian-Kai Wan, Wen-Wu Xu, Shang-Fu Yuan, Yi Gao*, Xiao-Cheng Zeng, and Quan-Ming Wang*. Near Infrared Emissive Alkynyl-Protected Au24 Nanocluster, Angew. Chem. Int. Ed. 2015 54, 9683-9686.

9. Xian-Kai Wan, Shang-Fu Yuan, Qing Tang, De-En Jiang*, and Quan-Ming Wang*. Alkynyl-Protected Au23 Nanocluster: A 12-Electron System, Angew. Chem. Int. Ed. 2015, 54, 5977-5980.

10. Xian-Kai Wan, Qing Tang, Shang-Fu Yuan, De-En Jiang*, and Quan-Ming Wang*. Au19 Nanocluster Featuring a V‑Shaped Alkynyl−Gold Motif, J. Am. Chem. Soc. 2015, 137, 652−655. (editor choice)

11. Xian-Kai Wan, Shang-Fu Yuan, Zhi-Wei Lin and Quan-Ming Wang*. Chiral Gold Nanocluster Au20 Protected by Tetradentate Phosphines, Angew. Chem. Int. Ed. 2014, 53, 5923-5926.

12. Xian-Kai Wan, Zhi-Wei Lin and Quan-Ming Wang*. Au20 Nanocluster Protected by Hemilabile Phosphines, J. Am. Chem. Soc. 2012, 134, 14750.

13. Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Zong-Jie Guan, Quan-Ming Wang*. Alkynyl Approach toward the Protection of Metal Nanoclusters, Acc. Chem. Res. 2018, 51, 2465.

14. Zhen Lei, Jiao-Jiao Li, Xian-Kai Wan, Wen-Han Zhang, Quan-Ming Wang*. Isolation and Total Structure Determination of an All AlkynylProtected Gold Nanocluster Au144. Angew. Chem. Int. Ed. 2018, 57, 8639.

15. Wang Yu, Xian-Kai Wan, Li-Ting Ren, Hai-Feng Su, Gang Li, Sami Malola, Shui-Chao Lin, Zi-Chao Tang, Hannu Häkkinen, Boon K Teo, Quan-Ming Wang*, Nan-Feng Zheng*. Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles, J. Am. Chem. Soc. 2016, 138, 3278-3281.

16. Zong-Jie Guan, Jiu-Lian Zeng, Zi-Ang Nan, Xian-Kai Wan, Yu-Mei Lin*, Quan-Ming Wang*. Thiacalix[4]arene: New protection for metal nanoclusters, Sci. Adv. 2016, 2, e1600323.

17. Xiao-Li Pei, Yang Yang, Zhen Lei, Shan-Shan Chang, Zong-Jie Guan, Xian-Kai Wan, Ting-Bin Wen, and Quan-Ming Wang*. Highly Active Gold(I)-Silver(I) Oxo Cluster Activating sp3 C-H Bonds of Methyl Ketones under Mild Conditions, J. Am. Chem. Soc. 2015, 137, 5520-5525.

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